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There are 5 nine-letter words containing XIV

CONNEXIVEconnexive adj. (Dated) connective.
connexive n. (Dated) connective.
CONNEXIVE adj. (obsolete) connective, also CONNECTIVE.
LIXIVIATElixiviate v. To separate (a substance) into soluble and insoluble components through percolation; to leach.
lixiviate adj. Of or relating to lye or lixivium; of the quality of alkaline salts.
lixiviate adj. Impregnated with salts from wood ashes.
LIXIVIOUSlixivious adj. Alternative form of lixivial.
LIXIVIOUS adj. impregnated with a salt or salts like a lixivium.
LIXIVIUMSlixiviums n. Plural of lixivium.
LIXIVIUM n. (Latin) a solution of alkaline salts extracted from wood ashes; hence, any solution obtained by lixiviation.
REFLEXIVEreflexive adj. (Grammar) Referring back to the subject, or having an object equal to the subject.
reflexive adj. (Mathematics) Of a relation R on a set S, such that xRx for all members x of S (that is, the relation…
reflexive adj. Of or resulting from a reflex.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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