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There are 3 twelve-letter words containing RCAP

DIMERCAPROLSDIMERCAPROL n. a compound developed as an antidote against lewisite and used to treat arsenic, mercury, and gold poisoning.
HYPERCAPNIAShypercapnias n. Plural of hypercapnia.
HYPERCAPNIA n. the presence of excessive amounts of carbon dioxide in the blood, also HYPERCARBIA.
OVERCAPACITYovercapacity n. A capacity for the production of a commodity or product that is in excess of what is needed.
OVERCAPACITY n. excessive capacity for production or services in relation to demand.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the 1Word.ws and WikWik.org.

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