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There are 10 ten-letter words containing LIOS

EMBROGLIOSembroglios n. Plural of embroglio.
EMBROGLIO n. (Italian) a confusing or disturbing situation, also IMBROGLIO.
HELIOSCOPEhelioscope n. (Astronomy) An apparatus for viewing the Sun without harming the eye, by means of an optical filter…
HELIOSCOPE n. an instrument for observing the sun without injury to the eyes.
HELIOSTATSheliostats n. Plural of heliostat.
HELIOSTAT n. an instrument using a mirror to reflect sunlight in a fixed direction, used for studying the sun or signalling messages.
IMBROGLIOSimbroglios n. Plural of imbroglio.
IMBROGLIO n. (Italian) a confusing or disturbing situation, also EMBROGLIO.
MILLIOSMOLmilliosmol n. A unit of measure, one thousandth of an osmol.
MILLIOSMOL n. one thousandth of an osmol, a unit of osmotic pressure.
PORTFOLIOSportfolios n. Plural of portfolio.
PORTFOLIO n. a case or pair of boards for holding loose papers.
PULVILLIOSpulvillios n. Plural of pulvillio.
PULVILLIO n. (historical) perfumed powder; snuff, also PULVIL, PULVILIO, PULVILLE.
PUNCTILIOSpunctilios n. Plural of punctilio.
PUNCTILIO n. (Italian) a minute detail of conduct; careful observance of forms.
SPADILLIOSSPADILLIO n. (obsolete) the ace of spades in the game of ombre, also SPADILLE, SPADILLO.
TELIOSPOREteliospore n. A teleutospore.
TELIOSPORE n. the thick-walled resting spore of rusts and smuts from which the basidium arises.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the 1Word.ws and WikWik.org.

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