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There are 2 twelve-letter words containing DOPE

ALDOPENTOSESaldopentoses n. Plural of aldopentose.
ALDOPENTOSE n. a type of sugar.
ENDOPEROXIDEendoperoxide n. (Chemistry, biochemistry) Any heterocycle containing a peroxide -O-O- residue in the ring; found especially…
ENDOPEROXIDE n. any of various biosynthetic intermediates in the formation of prostaglandins.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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