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There are 5 eight-letter words containing CATION

CATIONICcationic adj. (Chemistry) of, relating to, or being a cation.
CATIONIC adj. relating to a cation.
LOCATIONlocation n. A particular point or place in physical space.
location n. An act of locating.
location n. (South Africa) An apartheid-era urban area populated by non-white people; township.
PACATIONpacation n. (Formal) pacifying, placation.
PACATION n. appeasement.
VACATIONvacation n. Freedom from some business or activity.
vacation n. (Obsolete) Free time given over to a specific purpose; occupation, activity.
vacation n. A period during which official activity or business is formally suspended; an official holiday from…
VOCATIONvocation n. An inclination to undertake a certain kind of work, especially a religious career; often in response…
vocation n. An occupation for which a person is suited, trained or qualified.
VOCATION n. one's profession, business or occupation.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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