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There are 4 nine-letter words containing ANIO

CARBANIONcarbanion n. (Organic chemistry) any organic anion of general formula R3C-.
CARBANION n. an ion carrying a negative electrical charge at the carbon position.
COMPANIONcompanion n. A friend, acquaintance, or partner; someone with whom one spends time or accompanies.
companion n. (Dated) A person employed to accompany or travel with another.
companion n. (Nautical) The framework on the quarterdeck of a sailing ship through which daylight entered the cabins below.
GERANIOLSgeraniols n. Plural of geraniol.
GERANIOL n. an alcohol forming a constituent of many of the esters used in perfumery, also GERANIAL.
OXYANIONSoxyanions n. Plural of oxyanion.
OXYANION n. an anion containing one or more oxygen atoms bonded to another element (as in the sulphate and carbonate ions).

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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