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There is only one thirteen-letter word beginning with VITRIFIC

VITRIFICATIONvitrification n. (Usually uncountable) The action or process of vitrifying a material: conversion into a glass-like amorphous…
vitrification n. (Countable) An instance of such conversion.
vitrification n. (Countable) The result of such conversion: a vitrified substance or object.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org.

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