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There are 2 eight-letter words beginning with VALEN

VALENCESvalences n. Plural of valence.
VALENCE n. a chemical bond, also VALENCY.
VALENCIAvalencia n. A kind of woven fabric for waistcoats, having the weft of wool and the warp of silk or cotton.
Valencia prop.n. The capital city of the autonomous community of Valencia, Spain.
Valencia prop.n. An autonomous community of Spain, the Valencian Community.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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