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There are 4 twelve-letter words beginning with POLYSY

POLYSYLLABIC	• polysyllabic adj. (Of a word) Having more than one syllable; having multiple or many syllables. • polysyllabic adj. (Of spoken or written language) Characterized by or consisting of words having numerous syllables. • polysyllabic n. A word having more than one syllable.
POLYSYLLABLE	• polysyllable n. A word with more than two syllables. Sometimes used in a more restricted sense. • POLYSYLLABLE n. a polysyllabic word.
POLYSYNAPTIC	• polysynaptic adj. (Of a reflex or impulse) of or involving multiple synapses. • POLYSYNAPTIC adj. involving two or more synapses in the central nervous system.
POLYSYNDETON	• polysyndeton n. (Rhetoric) The use of many conjunctions to achieve an overwhelming effect in a sentence. • POLYSYNDETON n. the rhetorical device of repeating a conjunction for emphasis, as in 'it was red and yellow and pink and orange and blue!'.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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English Wiktionary: 8 words
Scrabble in French: 2 words
Scrabble in Spanish: no word
Scrabble in Italian: no word
Scrabble in German: no word
Scrabble in Romanian: no word

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