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There are 7 eight-letter words beginning with PENTA

PENTACLEpentacle n. A flat talisman, almost always star-shaped, made of parchment, sheet metal, or other substance, marked…
pentacle n. (Wicca) A pentagram, or a disk with a pentagram on it, especially one that is used for magical or mystical purposes.
pentacle n. (Wicca) A circumscribed pentagram.
PENTACTSpentacts n. Plural of pentact.
PENTACT n. a five-rayed structure in a sponge.
PENTADICpentadic adj. Of, or relating to a pentad.
PENTADIC adj. within the scope of a pentad.
PENTAGONpentagon n. (Geometry) A polygon with five sides and five angles.
pentagon n. A fort with five bastions.
Pentagon prop.n. The headquarters of the United States Department of Defense.
PENTANESpentanes n. Plural of pentane.
PENTANE n. any of three hydrocarbons of the methane or paraffin series.
PENTANOLpentanol n. (Organic chemistry) Any of several isomers of the alcohol C5H11OH; the principal constituents of fusel…
PENTANOL n. one of the simple alcohols.
PENTARCHpentarch n. A member of a pentarchy.
PENTARCH n. a member of a pentarchy, government by five persons.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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