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There are 3 fourteen-letter words beginning with POLAR

POLARISABILITYpolarisability n. Alternative spelling of polarizability.
POLARISABILITY n. the ability to be polarised.
POLARIZABILITYpolarizability n. (Physics) The relative tendency of a system of electric charges to become polarized in the presence…
POLARIZABILITY n. the state of being polarizable.
POLAROGRAPHIESpolarographies n. Plural of polarography.
POLAROGRAPHY n. a technique for determining the concentration and nature of the ions in a solution by an electrolytic process.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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