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There are 4 eleven-letter words beginning with PILO

PILOCARPINEpilocarpine n. (Biochemistry, pharmacology) A miotic alkaloid C11H16N2O2 obtained from jaborandi that is used chiefly…
PILOCARPINE n. an alkaloid obtained from jaborandi leaves, also PILOCARPIN.
PILOCARPINSPILOCARPIN n. an alkaloid obtained from jaborandi leaves, also PILOCARPINE.
PILOTFISHESpilotfishes n. Plural of pilotfish.
pilot␣fishes n. Plural of pilot fish.
PILOTFISH n. a tropical fish.
PILOTHOUSESpilothouses n. Plural of pilothouse.
PILOTHOUSE n. a shelter for steering gear and pilot.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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