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There are 3 ten-letter words beginning with PLEX

PLEXIGLASS	• plexiglass n. Polymethyl methacrylate (polymer of methyl methacrylate), a tough transparent plastic used sometimes in lieu of glass. • Plexiglass n. Misspelling of Plexiglas. • PLEXIGLASS n. acrylic plastic sheets.
PLEXIMETER	• pleximeter n. (Medicine) A small, hard, elastic plate, as of ivory, bone, or rubber, placed in contact with the body… • PLEXIMETER n. a small plate to receive the tap in examination by percussion, also PLESSIMETER.
PLEXIMETRY	• pleximetry n. The use of the pleximeter. • PLEXIMETRY n. the use of a pleximeter, a small, hard, elastic plate, as of ivory, bone, or rubber, placed in contact with body to receive the blow, in examination by mediate percussion.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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English Wiktionary: 11 words
Scrabble in French: no word
Scrabble in Spanish: no word
Scrabble in Italian: no word
Scrabble in German: no word
Scrabble in Romanian: 2 words

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