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There is only one two-letter word beginning with PI

PIpi n. The 16th letter of the Classical and Modern Greek alphabets and the seventeenth in Old Greek.
pi n. (Mathematics) An irrational and transcendental constant representing the ratio of the circumference…
pi n. (Letterpress typography) Metal type that has been spilled, mixed together, or disordered.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org.

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