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There are 3 eight-letter words beginning with MEDIAT

MEDIATEDmediated v. Simple past tense and past participle of mediate.
MEDIATE v. to act as an intermediary.
MEDIATESmediates v. Third-person singular simple present indicative form of mediate.
MEDIATE v. to act as an intermediary.
MEDIATORmediator n. One who negotiates between parties seeking mutual agreement.
mediator n. A chemical substance transmitting information to a targeted cell.
MEDIATOR n. one who mediates.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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