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There are 3 fifteen-letter words beginning with LIGN

LIGNOCELLULOSES	• lignocelluloses n. Plural of lignocellulose. • LIGNOCELLULOSE n. any of several compounds of lignin and cellulose occurring in woody tissue.
LIGNOCELLULOSIC	• lignocellulosic adj. (Biochemistry) Of, pertaining to, or derived from lignocellulose; used especially to describe the products of biomass. • lignocellulosic n. Any material composed of lignocellulose. • LIGNOCELLULOSIC adj. of or like lignocellulose.
LIGNOSULFONATES	• lignosulfonates n. Plural of lignosulfonate. • LIGNOSULFONATE n. any of various compounds produced from the spent sulfite liquor in the pulping of softwood in papermaking and used esp. for binders and dispersing agents.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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English Wiktionary: 6 words
Scrabble in French: no word
Scrabble in Spanish: 2 words
Scrabble in Italian: 5 words
Scrabble in German: no word
Scrabble in Romanian: 1 word

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