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There are 4 fourteen-letter words beginning with LIG

LIGHTHEARTEDLYlightheartedly adv. In a lighthearted manner, cheerfully, with joy.
light-heartedly adv. Alternative form of lightheartedly.
LIGHTHEARTED adv. free from care.
LIGNIFICATIONSlignifications n. Plural of lignification.
LIGNIFICATION n. the act of lignifying, turning to wood.
LIGNOCELLULOSElignocellulose n. (Biochemistry) The combination of lignin and cellulose in the structural cells of woody plants.
LIGNOCELLULOSE n. any of several compounds of lignin and cellulose occurring in woody tissue.
LIGNOSULFONATElignosulfonate n. Any sulfonated derivative of a lignin.
LIGNOSULFONATE n. any of various compounds produced from the spent sulfite liquor in the pulping of softwood in papermaking and used esp. for binders and dispersing agents.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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