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There are 3 nine-letter words beginning with IRIS

IRISATINGirisating adj. Exhibiting the prismatic colours; iridescent.
IRISATE v. to make iridescent.
IRISATIONirisation n. (Meteorology) A colorful optical phenomenon seen in iridescent clouds and on the borders of lenticular…
IRISATION n. iridescence.
IRISCOPESiriscopes n. Plural of iriscope.
IRISCOPE n. an instrument showing colours of a prism.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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