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There are 5 eleven-letter words beginning with ION

IONISATIONSionisations n. Plural of ionisation.
IONISATION n. the act of ionising, also IONIZATION.
IONIZATIONSionizations n. Plural of ionization.
IONIZATION n. the act of ionizing, also IONISATION.
IONOSPHERESionospheres n. Plural of ionosphere.
IONOSPHERE n. a region of the upper atmosphere.
IONOSPHERICionospheric adj. Of or pertaining to the ionosphere.
IONOSPHERIC adj. relating to the ionosphere.
IONOTROPIESIONOTROPY n. the reversible interconversion of a pair of organic isomers.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the 1Word.ws and WikWik.org.

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