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There are 3 nine-letter words beginning with HERC

HERCOGAMY	• hercogamy n. (Botany) The condition where self-pollination is impossible (e.g. due to physical obstacles or mutations). • HERCOGAMY n. the prevention of self-pollination in plants, also HERKOGAMY.
HERCULEAN	• herculean adj. Alternative letter-case form of Herculean. • Herculean adj. Of extraordinary might, power, size, etc.; suggesting Hercules in size or strength. • Herculean adj. Requiring a huge amount of work; of extraordinary difficulty.
HERCYNITE	• hercynite n. (Mineralogy) An isometric-hexoctahedral black mineral containing aluminum, iron, and oxygen. • HERCYNITE n. black spinel, an aluminate of iron.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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English Wiktionary: 16 words
Scrabble in French: 12 words
Scrabble in Spanish: 8 words
Scrabble in Italian: no word
Scrabble in German: no word
Scrabble in Romanian: 4 words

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