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There are 14 eight-letter words beginning with HEX

HEXAFOILhexafoil n. A design with six round semicircular petals stemming from a central circle.
HEXAFOIL n. a pattern with six leaflike lobes.
HEXAGLOThexaglot adj. (Rare) In six languages.
HEXAGLOT n. a book written in six languages.
HEXAGONShexagons n. Plural of hexagon.
HEXAGON n. a polygon having six sides.
HEXAGRAMhexagram n. A hollow six-pointed star formed by overlapping two equilateral triangles.
hexagram n. Any of the 64 sets of solid and broken lines, formed by pairs of trigrams, used for divination in the I Ching.
hexagram n. A large silver coin minted during the Byzantine Empire.
HEXAMINEhexamine n. (Organic chemistry) Contraction of hexamethylenetetramine.
HEXAMINE n. a chemical compound, used as a solid fuel.
HEXANOIChexanoic adj. Of or pertaining to hexanoic acid or its derivatives; caproic.
HEXANOIC adj. as in hexanoic acid, a component of palm oil.
HEXAPLARHexaplar adj. Being or relating to a Hexapla.
HEXAPLAR adj. relating to a hexapla, an edition of the bible in six languages, also HEXAPLARIAN, HEXAPLARIC.
HEXAPLAShexaplas n. Plural of hexapla.
Hexaplas n. Plural of Hexapla.
HEXAPLA n. (Greek) a book of six (especially Biblical) parallel texts.
HEXAPODShexapods n. Plural of hexapod.
HEXAPOD n. an animal with six feet, an insect.
HEXAPODYhexapody n. (Poetry, countable) Six metrical feet taken together, or included in one measure.
hexapody n. (Zoology, uncountable) The property of being a hexapod; six-leggedness.
HEXAPODY n. a line of verse with six feet.
HEXARCHYhexarchy n. A group of six states.
HEXARCHY n. a group of six separate states.
HEXEREIShexereis n. Plural of hexerei.
HEXEREI n. (German) witchcraft.
HEXOSANShexosans n. Plural of hexosan.
HEXOSAN n. a polysaccharide that yields hexose on hydrolysis.
HEXYLENEhexylene n. (Chemistry) A colourless liquid hydrocarbon, C6H12, of the ethylene series, produced artificially, and…
hexylene n. (Chemistry) Any of several isomers of hexylene proper.
HEXYLENE n. a colorless, liquid hydrocarbon of the ethylene series, also HEXENE.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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