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There is only one twelve-letter word beginning with CARDIOP

CARDIOPLEGIAcardioplegia n. (Surgery) The deliberate, temporary cessation of cardiac activity before heart surgery.
CARDIOPLEGIA n. deliberate arrest of the action of the heart, as by hypothermia or the injection of chemicals, to enable complex heart surgery to be carried out.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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