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There are 6 ten-letter words beginning with CATEN

CATENACCIOcatenaccio n. (Soccer) A system of defensive play focused on nullifying opponents’ attacks and preventing goal-scoring…
CATENACCIO n. (Italian) a defensive system of play in football.
CATENARIANcatenarian adj. Catenary; like a chain.
CATENARIAN adj. of or pertaining to chains.
CATENARIEScatenaries n. Plural of catenary.
CATENARY n. a curve of the kind formed by a uniform chain hanging freely from two points not in the same vertical line.
CATENATINGcatenating v. Present participle of catenate.
CATENATE v. to link together.
CATENATIONcatenation n. The act or process of catenating.
catenation n. (Chemistry) The ability of a few elements, most especially carbon, to yield chains and rings by forming…
CATENATION n. connection of links or union of parts, as in a chain; a regular or connected series.
CATENULATEcatenulate adj. (Botany, zoology) In the form of a chain of linked parts.
catenulate v. To form into a chain.
CATENULATE adj. of certain spores, formed in a row or chain.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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