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There are 4 ten-letter words beginning with CITR

CITRONELLAcitronella n. A tropical Asian grass, Cymbopogon nardus, that has citrus-scented leaves.
citronella n. An essential oil obtained from this plant, often used as an insect repellent.
CITRONELLA n. a colourless aldehyde with a lemon scent.
CITRULLINEcitrulline n. (Biochemistry) An amino acid, first isolated from watermelons, that is an intermediate in the urea cycle.
CITRULLINE n. an amino acid formed in the production of urea.
CITRUSIESTCITRUSY adj. pertaining to citrus, also CITRUSSY.
CITRUSSIERCITRUSSY adj. of or like citrus fruit, also CITRUSY.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the 1Word.ws and WikWik.org.

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