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There are 5 ten-letter words beginning with CAF

CAFETERIAScafeterias n. Plural of cafeteria.
caféterias n. Plural of caféteria.
cafétérias n. Plural of cafétéria.
CAFETIEREScafetieres n. Plural of cafetiere.
cafetières n. Plural of cafetière.
CAFETIERE n. (French) a type of coffee-maker.
CAFETORIUMcafetorium n. A large room, usually in a school, used as both a cafeteria and an auditorium.
CAFETORIUM n. a large room designed for use as both a cafe and an auditorium.
CAFFEINATEcaffeinate v. (Transitive) To add caffeine to.
caffeinate v. (Intransitive, slang) To drink caffeinated beverages in order to increase one’s energy or wakefulness…
caffeinate v. (Transitive, slang) To inject tension into (A situation, etc.) for one’s own amusement; to stir things up.
CAFFEINISMcaffeinism n. A toxic condition caused by excessive ingestion of coffee and other caffeine-containing beverages.
caffeinism n. Addiction to such beverages.
CAFFEINISM n. an unhealthy condition caused by taking too much caffeine.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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