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There are 3 eight-letter words beginning with BARBI

BARBICANbarbican n. A tower at the entrance to a castle or fortified town.
barbican n. A fortress at the end of a bridge.
barbican n. An opening in the wall of a fortress through which the guns are levelled; a narrow loophole through…
BARBICELbarbicel n. Any of the hooks on the barbules of a feather that interlock adjacent barbs.
BARBICEL n. one of the small hooklike processes on the barbules of feathers.
BARBITALbarbital n. The first commercially marketed barbiturate, used as a hypnotic drug until the mid-1950s.
BARBITAL n. (US) a derivative of barbituric acid used as a sedative, also BARBITONE.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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