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There are 13 nine-letter words beginning with ALA

ALABAMINEalabamine n. (Obsolete) Former name for the chemical element astatine.
ALABAMINE n. an alternative name for the element astatine.
ALABASTERalabaster n. A fine-grained white or lightly-tinted variety of gypsum, used ornamentally.
alabaster n. (Historical) A variety of calcite, translucent and sometimes banded.
alabaster n. (Color) An off-white colour, like that of alabaster.
ALACHLORSALACHLOR n. a type of herbicide.
ALACKADAYalackaday interj. Synonym of alack.
ALACKADAY interj. an expression of regret or deprecation, also LACKADAY.
ALAIMENTSALAIMENT n. an allayment, a lessening.
ALALAGMOIalalagmoi n. Plural of alalagmos.
ALALAGMOS n. (Greek) a war-cry of 'alalai'.
ALALAGMOSalalagmos n. (Historical) A war cry of Ancient Greece.
ALALAGMOS n. (Greek) a war-cry of 'alalai'.
ALARMABLEalarmable adj. Easily alarmed; excitable.
alarmable adj. (Rare) Of a building, etc.: capable of being fitted with an alarm system.
ALARMABLE adj. that can be alarmed.
ALARMEDLYalarmedly adv. In an alarmed manner.
ALARMED adv. ALARM, to strike with fear.
ALARMISMSalarmisms n. Plural of alarmism.
ALARMISM n. the practice of alarming others needlessly.
ALARMISTSalarmists n. Plural of alarmist.
ALARMIST n. one who alarms others needlessly.
ALARUMINGalaruming v. (Archaic, rare) present participle of alarum.
ALARUM v. (archaic) to alarm, also LARUM.
ALASTRIMSALASTRIM n. (Portuguese) a mild form of smallpox.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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