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There are 4 five-letter words beginning with ACT

ACTEDacted v. Simple past tense and past participle of act.
ACT v. to do something in a specified way.
ACTINactin n. (Biochemistry, uncountable) A globular structural protein that polymerizes in a helical fashion to form…
actin n. (Biochemistry, countable) One of the six isoforms of actin.
actin' v. Pronunciation spelling of acting.
ACTONacton n. Alternative form of aketon.
acton n. Obsolete form of actinon.
Acton prop.n. (Uncountable) Any of a few places in England…
ACTORactor n. (Obsolete, law) Someone who institutes a legal suit; a plaintiff or complainant.
actor n. (Obsolete) Someone acting on behalf of someone else; a guardian.
actor n. Someone or something that takes part in some action; a doer, an agent.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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