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There are 14 fourteen-letter words beginning with AST

ASTHENOSPHERESasthenospheres n. Plural of asthenosphere.
ASTHENOSPHERE n. the upper layer of the earth's mantle, below the lithosphere, characterized by a relatively low resistance to plastic flow.
ASTHENOSPHERICasthenospheric adj. (Geology) Of, pertaining to, or arising from the asthenosphere, the soft area of the upper mantle.
ASTHENOSPHERIC adj. relating to the asthenosphere.
ASTIGMATICALLYastigmatically adv. In an astigmatic manner; through or in relation to astigmatism.
ASTIGMATIC adv. affected with, or pertaining to, astigmatism.
ASTRAPOPHOBIASASTRAPOPHOBIA n. a morbid fear of thunder and lightning, also ASTRAPHOBIA, ASTROPHOBIA.
ASTROBIOLOGIESASTROBIOLOGY n. exobiology.
ASTROBIOLOGISTastrobiologist n. A biologist whose speciality is astrobiology.
ASTROBIOLOGIST n. one who studies astrobiology.
ASTROCHEMISTRYastrochemistry n. (Chemistry, astronomy) The study of the chemical composition of stars and outer space.
ASTROCHEMISTRY n. the study of molecules and radicals in outer space.
ASTROCOMPASSESastrocompasses n. Plural of astrocompass.
ASTROCOMPASS n. a navigational instrument for giving directional bearings from the centre of the earth to a particular star.
ASTROGEOLOGIESASTROGEOLOGY n. the study of extraterrestrial geology.
ASTROGEOLOGISTastrogeologist n. One who studies astrogeology.
ASTROGEOLOGIST n. a specialist in astrogeology.
ASTROLOGICALLYastrologically adv. In an astrological manner.
astrologically adv. With regard to astrology.
ASTROLOGICAL adv. relating to astrology, also ASTROLOGIC.
ASTRONAVIGATORastronavigator n. One who performs astronavigation; an astronaut or space pilot.
ASTRONAVIGATOR n. one who practises astronavigation.
ASTRONOMICALLYastronomically adv. (Not comparable) Of or relating to astronomy.
astronomically adv. (Comparable, degree) In the extreme, very (typically very large).
ASTRONOMICAL adv. related to astronomy, also ASTRONOMIC.
ASTROPHYSICISTastrophysicist n. One who studies astrophysics.
ASTROPHYSICIST n. a student of astrophysics.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the 1Word.ws and WikWik.org.

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