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There are 15 four-letter words beginning with AC

ACAIacai n. Any of several South American palms, of the genus Euterpe, having a dark purple drupe.
acai n. The fruit of these trees, harvested for its juice.
açai n. Alternative spelling of acai.
ACCAacca n. (Slang) An accumulator bet.
Acca prop.n. A taxonomic genus within the family Myrtaceae – the feijoa or pineapple guava and closely related shrubs…
Acca prop.n. A taxonomic genus within the family Nymphalidae – sometimes including in genus Pantoporia.
ACEDaced v. Simple past tense and past participle of ace.
ACE v. to serve an unreturnable shot e.g. in tennis.
ACERacer n. A plant of the genus Acer; a maple.
acer n. Obsolete spelling of acre.
Acer prop.n. A taxonomic genus within the family Sapindaceae – the maples.
ACESaces n. Plural of ace.
aces v. Third-person singular simple present indicative form of ace.
aces adj. (Informal) Alternative form of ace (“excellent”).
ACHEache v. (Intransitive) To suffer pain; to be the source of, or be in, pain, especially continued dull pain; to be distressed.
ache v. (Transitive, literary, rare) To cause someone or something to suffer pain.
ache n. Continued dull pain, as distinguished from sudden twinges, or spasmodic pain.
ACHYachy adj. Suffering from aches, sore.
ACHY adj. aching.
ACIDacid adj. Sour, sharp, or biting to the taste; tart; having the taste of vinegar.
acid adj. (Figuratively) Sour-tempered.
acid adj. Of or pertaining to an acid; acidic.
ACMEacme n. A high point: the highest point of any range, the most developed stage of any process, or the culmination…
acme n. A paragon: a person or thing representing such a high point.
acme n. (Rare) Full bloom or reproductive maturity.
ACNEacne n. (Pathology) A skin condition, usually of the face, that is common in adolescents. It is characterised…
acne n. A pattern of blemishes in an area of skin resulting from the skin condition.
ACNE n. a skin disease caused by inflammation of the sebaceous follicles, esp. on the face, neck, and shoulders.
ACREacre n. An English unit of land area (Symbol: a. or ac.) originally denoting a day’s ploughing for a yoke of…
acre n. Any of various similar units of area in other systems.
acre n. (Informal, usually in the plural) A wide expanse.
ACROacro adj. Of or pertaining to something that combines acrobatic elements with that of something else.
acro n. Acrobatic gymnastics.
acro n. Misspelling of acrow.
ACTAACTA prop.n. Initialism of Anti-Counterfeiting Trade Agreement.
ACTA n. (Latin) official minutes of proceedings.
ACTSacts n. Plural of act.
acts v. Third-person singular simple present indicative form of act.
Acts prop.n. (Biblical) Clipping of Acts of the Apostles.
ACYLacyl n. (Organic chemistry) Any of class of organic radicals, RCO-, formed by the removal of a hydroxyl group…
ACYL n. an organometallic compound.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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