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There are 9 ten-letter words containing 2L, O, P and V

ISOPLUVIALISOPLUVIAL n. a line on a map connecting places registering the same amount of precipitation or rainfall.
OVERSPILLSoverspills v. Third-person singular simple present indicative form of overspill.
overspills n. Plural of overspill.
OVERSPILL v. to spill over.
POLYVALENTpolyvalent adj. Multivalent; having a number of different forms, purposes, meanings, aspects or principles.
polyvalent adj. (Chemistry) Having a high valence, especially more than three.
polyvalent adj. (Chemistry) Having multiple valencies.
POLYVINYLSpolyvinyls n. Plural of polyvinyl.
POLYVINYL n. a vinyl polymer.
PULVILLIOSpulvillios n. Plural of pulvillio.
PULVILLIO n. (historical) perfumed powder; snuff, also PULVIL, PULVILIO, PULVILLE.
SLAVOPHILESlavophile n. A person who is interested in the development and prosperity of the Slavic race.
SLAVOPHILE n. a person who admires the Slavs or their culture, also SLAVOPHIL.
SLAVOPHILSSlavophils n. Plural of Slavophil.
SLAVOPHIL n. a person who admires the Slavs or their culture, also SLAVOPHILE.
SPILLOVERSspillovers n. Plural of spillover.
SPILLOVER n. an overflow.
VOLPLANINGvolplaning v. Present participle of volplane.
VOLPLANE v. to glide in an aeroplane.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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