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There are 2 fourteen-letter words containing D, 2L, 2N and V

NOVEMDECILLIONnovemdecillion num. (US; modern British & Australian, short scale, rare) 1060.
novemdecillion num. (Dated British & Australian, long scale, rare) 10114.
novemdecillion num. A very large number.
POLYVINYLIDENEpolyvinylidene n. (Chemistry) Any polymer derived from monomers of general formula CH2=CX2 where X is typically a halogen.
polyvinylidene n. A polyvinylidene resin.
POLYVINYLIDENE n. any polymer derived from halogen monomers.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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