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There are 5 eight-letter words containing A, 2I, 2L, N and V

VANILLICvanillic adj. (Organic chemistry) Of or pertaining to vanillin or vanillic acid.
VANILLIC adj. pertaining to, or derived from, vanilla.
VANILLINvanillin n. A chemical compound, 4-hydroxy-3-methoxybenzaldehyde, that is the primary constituent of vanilla.
vanillin n. Synthetic compound used as a substitute for the extract of the vanilla bean.
VANILLIN n. a white crystalline aldehyde having a burning taste and characteristic odor of vanilla, extracted from vanilla pods.
VIALLINGvialling v. Present participle of vial.
VIAL v. to put in a small container for liquids.
VILLAINSvillains n. Plural of villain.
VILLAIN n. a malevolent evildoer, also VILLAN.
VILLAINYvillainy n. (Uncountable) Evil or wicked character or behaviour.
villainy n. (Countable) A wicked or treacherous act.
villainy n. (Uncountable, obsolete) Ill-treatment, indignity, degrading or shameful treatment of someone.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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