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There are 10 twelve-letter words containing 2A, F, I and V

ACRIFLAVINESacriflavines n. Plural of acriflavine.
ACRIFLAVINE n. an antiseptic, also ACRIFLAVIN.
AFFIRMATIVESaffirmatives n. Plural of affirmative.
AFFIRMATIVE n. an expression of affirmation or assent.
AFFRICATIVESaffricatives n. Plural of affricative.
AFFRICATIVE n. a sound like an affricate.
FACILITATIVEfacilitative adj. Having the effect of making easy; assisting, easing or facilitating.
FACILITATIVE adj. serving to facilitate.
FAVORABILITYfavorability n. The quality or degree of being viewed favorably.
favorability n. Something which is favorable.
LACTOFLAVINSlactoflavins n. Plural of lactoflavin.
LACTOFLAVIN n. an earlier name for riboflavin.
OVERFAMILIARoverfamiliar adj. Common or repeated to the point of being unnoticed or annoying.
overfamiliar adj. (Used with “with”) So acquainted with something, that one doesn’t notice it, or is annoyed by it.
overfamiliar adj. Overly friendly or intimate.
PARVIFOLIATEPARVIFOLIATE adj. of plants, having small leaves in comparison with the size of the stem.
SALVIFICALLYsalvifically adv. For the purpose of salvation.
SALVIFICAL adv. (obsolete) having the purpose or intention of saving, also SALVIFIC.
TRYPAFLAVINEtrypaflavine n. An acridine dye thought to be identical with flavine or acriflavine.
TRYPAFLAVINE n. another name for acriflavine.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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